Individual Solvation Numbers around the Nickel (II) Ion in an N,N-Dimethylformamide and N,N-Dimethylacetamide Mixture Determined by Raman Spectrophotometry.

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Individual solvation numbers around the nickel(II) ion in an N,N-dimethylformamide and N,N-dimethylacetamide mixture determined by Raman spectrophotometry.

Individual solvation numbers around the nickel(II) ion have been determined by titration Raman spectroscopy in N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) mixtures at 298 K. The in-plane bending vibration (delta(O=C-N)) of DMF and the stretching vibration (v(N-CH3)) of DMA were used in the present analysis. These Raman bands of solvent molecules shift to higher frequencies upon ...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2001

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.17.323